Productie 10 - Quickscan emissies

RIVM-briefrapport 2022-0235

lijke gezondheid door verwacht. Het geschatte broeikaseffect door het lekken van SF6 uit windturbines op land wordt geschat op <0,01% van de klimaatwinst door de opwekking van energie. Hoewel de klimaatimpact van gebruik van SF6 in windturbines klein geschat wordt vergeleken de klimaatwinst, is het vanwege de trage afbreeksnelheid van de stof wenselijk om de emissie zo veel mogelijk te beperken. Dit sluit aan bij vigerend beleid van de EU. De windsector werkt momenteel aan alternatieven voor SF6. Het verdient aanbeveling om deze ontwikkelingen nauwlettend te volgen om zo het gebruik van SF6 op termijn terug te kunnen dringen. Om meer inzicht te verkrijgen in mogelijke risico’s door uitloging en slijtage van coatings bij windturbines op land zijn er diverse opties voor vervolgonderzoek: • Meer specifieke informatie over de samenstelling van de coatings die daadwerkelijk op Nederlandse windturbines worden gebruikt. • Op basis van modelleren een risicobeoordeling maken voor de stoffen die kunnen uitlogen uit de specifieke turbine coatings (zie bovenstaande bullet). Het is mogelijk om een schatting te maken van de hoeveelheid stof die uitloogt. Met behulp van verspreidingsmodellen kan vervolgens een concentratie in het milieu worden berekend. Deze concentraties kunnen dan worden vergeleken met normen om de risico’s voor mens en milieu te beoordelen.

• Uitlogingstesten van coatings gebruikt bij windturbines op land. • Bioassays met water van uitlogingstesten met coatings gebruikt bij windturbines. • Inzicht in welke mate leading edge protection (LEP) in Nederland wordt toegepast. • Meten van erosie en emissie (gewicht, aantal deeltjes, deeltjesgrootte) van coatings op turbinebladen (inclusief emissie door onderhoud). • Metingen van in coatings gebruikte stoffen in water en bodem in een gradiënt rondom windturbines. • Metingen van (micro)plastics in water en bodem in een gradiënt rondom windturbines.

Pagina 34 van 49

RIVM-briefrapport 2022-0235

7

Dankwoord

De auteurs bedanken hun RIVM-collega’s Willie Peijnenburg, Joost Bakker, Piet Otte, Johannes Lijzen en Meinie Naus voor hun bijdragen aan dit rapport.

Pagina 35 van 49

RIVM-briefrapport 2022-0235

Pagina 36 van 49

RIVM-briefrapport 2022-0235

8

Bronnen

Bell, A. M., Baier, R., Kocher, B., Reifferscheid, G., Buchinger, S., & Ternes, T. (2020). Ecotoxicological characterization of emissions from steel coatings in contact with water. Water research, 173, 115525. Bell, A. M., Keltsch, N., Schweyen, P., Reifferscheid, G., Ternes, T., & Buchinger, S. (2021). UV aged epoxy coatings ̶ Ecotoxicological effects and released compounds. Water Research X, 12, 100105. BIPRO. (2015). Epoxy resins in wind energy applications. https://epoxyeurope.eu/wpcontent/uploads/2015/07/epoxy_erc_bpa_whitepapers_windenergy-2.pdf Bruchet, A., Elyasmino, N., Decottignies, V., & Noyon, N. (2014). Leaching of bisphenol A and F from new and old epoxy coatings: Laboratory and field studies. Water Science and Technology: Water Supply, 14(3), 383-389. Burges, K. D., Michael; Hussy, Charlotte; Rhiemeier, Jan-Martin; Franck, Christian; Rabie, Mohamed. (2018). Concept for SF6-free transmission and distribution of electrical energy. Cantoni, B., Riguzzi, A. C., Turolla, A., & Antonelli, M. (2021). Bisphenol A leaching from epoxy resins in the drinking water distribution networks as human health risk determinant. Science of The Total Environment, 783, 146908. CBS.

Hoeveel uitstoot veroorzaakt het Nederlandse vervoer over land? Retrieved 01-12-2022 from https://www.cbs.nl/nlnl/visualisaties/verkeer-en-vervoer/uitstoot-enbrandstofverbruik/uitstoot-vervoer-over-land CBS. Vermeden verbruik fossiele energie en emissie CO2. Retrieved 0112-2022 from https://www.cbs.nl/nl-nl/cijfers/detail/84918NED coating.co.uk. Wind Turbine Coatings. Retrieved 30-11-2022 from https://www.coating.co.uk/wind-turbine-coatings/ Groshart, C. P., Okkerman, P. C., & Pijnenburg, A. M. C. M. (2001). Chemical study on Bisphenol A (RIKZ/2001.027). IPCC. (2006). Guidelines for National Greenhouse Gas Inventories. Volume 3: Industrial Processes and Product Use. https://www.ipcc-nggip.iges.or.jp/public/2006gl/vol3.html Mishnaevsky Jr, L. (2019). Repair of wind turbine blades: Review of methods and related computational mechanics problems. Renewable energy, 140, 828-839. Mishnaevsky Jr, L., Branner, K., Petersen, H. N., Beauson, J., McGugan, M., & Sørensen, B. F. (2017). Materials for wind turbine blades: An overview. Materials, 10(11), 1285. Mishnaevsky Jr, L., Fæster, S., Mikkelsen, L. P., Kusano, Y., & Bech, J. I. (2020). Micromechanisms of leading edge erosion of wind turbine blades: X‐ray tomography analysis and computational studies. Wind Energy, 23(3), 547-562. Momber, A. W., & Marquardt, T. (2018).

Protective coatings for offshore wind energy devices (OWEAs): a review. Journal of Coatings Technology and Research, 15(1), 13-40. https://doi.org/10.1007/s11998-017-9979-5 Pagina 37 van 49

RIVM-briefrapport 2022-0235

Pugh, K., & Stack, M. (2021). Rain erosion maps for wind turbines based on geographical locations: A case study in Ireland and Britain. Journal of Bio-and Tribo-Corrosion, 7(1), 1-7. Razdan, P., & Garrett, P. (2015). Life Cycle Assessment of electricity production from an onshore V110-2.0 MW wind plant. Razdan, P., & Garrett, P. (2017). Life Cycle Assessment of electricity production from an Onshore V112-3.45 MW Wind Plant. RIVM. (2022). Inzicht in emissies van chemische stoffen bij windturbines op zee. https://www.rivm.nl/sites/default/files/202206/Chemische_stoffen_bij_windturbines_op_zee_TG.pdf Russ, M. R.-M., Lana. (2020). Life Cycle Assessment of a Nordex Wind Farm with Delta4000 Turbines. RVO. (2022). Monitor Wind op Land over 2021. https://www.rvo.nl/onderwerpen/windenergie-op-land/monitor Shankar Verma, A., Jiang, Z., Ren, Z., Caboni, M., Verhoef, H., van der Mijle‐Meijer, H., Castro, S. G., & Teuwen, J. J. (2021a). A probabilistic long‐term framework for site‐specific erosion analysis of wind turbine blades: A case study of 31 Dutch sites. Wind Energy, 24(11), 1315-1336. Shankar Verma, A., Noi, S. D., Ren, Z., Jiang, Z., & Teuwen, J. J. E. (2021b). Minimum Leading Edge Protection Application Length to Combat RainInduced Erosion of Wind Turbine Blades. Energies, 14(6), 1629. https://doi.org/10.3390/en14061629 Urbanus, J.

H., Brunner, A., Boersma, A., Henke, S., Kooter, I., Lensen, S., Parker, L., Schwarz, A., Imhof, P., Dortmans, A., & Wijngaard, M. (2022). Microplastics are everywhere: 70% reduction achievable. https://www.tno.nl/en/newsroom/2022/11/sourcesmicroplastics-the-netherlands/ Vermeirssen, E. L., Dietschweiler, C., Werner, I., & Burkhardt, M. (2017). Corrosion protection products as a source of bisphenol A and toxicity to the aquatic environment. Water research, 123, 586-593. World Health Organization (2017). Dietary and inhalation exposure to nano- and microplastic particles and potential implications for human health. https://www.who.int/publications/i/item/9789240054608 Zhang, S., Kiil, S., Dam-Johansen, K., & Bernad Jr, P. (2014). Accelerated rain erosion of wind turbine blade coatings. Danmarks Tekniske Universitet (DTU).

Pagina 38 van 49

RIVM-briefrapport 2022-0235

Bijlagen

Informatievraag producenten (Engels) In order to gain insight in emissions of (and subsequent potential environmental risks) of substances used in wind turbines in the Netherlands we are looking for the information listed below. We are focusing on emissions during the use-phase of the turbines, so not during production, installation, etc. We are looking for information on multiple types of turbine and are interested in both onshore and offshore turbines (as complete as possible). If this is not feasible, we would like the information for the most commonly used coatings for both land and sea. Furthermore we are interested in any differences in used material, maintenance, or emissions of substances: • Between turbines on land and offshore • Between generations (old vs new turbines) • Between different sizes of turbines • Between locations (e.g., leading edge erosion near coast or more inland) We would also like to acknowledge that it might not be possible for every question to be answered in the level of detail requested, but any information that can be given will be very helpful.

Preferably we would like to receive the information in digital form (e.g., excel sheet of product composition), and in level of detail according to the following hierarchy: • Composition of used product • Presence of substances of very high concern and their concentrations • Safety data sheets • Name of product List of requested information Material composition information on coatings of wind turbine blades • • • • • •

What coatings are used? What is the layering of the coatings/in what order are the coatings applied on the blade? What is their material composition? Are any substances used that are listed on the ECHA candidate list of substances of very high concern (SVHC) If so, in what amounts? Are PFAS/fluoropolymers used in wind turbine blades? Where and in what amounts?

Leading Edge Erosion We are interested in how much material is emitted due to leading edge erosion. So we are looking on information on the amount of weight over time, and which layers or substances erode/are emitted. Data on mass loss of wind turbine blades or data on how much new material is applied during maintenance could be of use for this. Pagina 39 van 49

RIVM-briefrapport 2022-0235

• • • •

How much material (weight) is lost over time? Which layers are affected? (ideally weight loss per layer/time unit) Alternatively, information of thickness and density of the layers in addition to loss of volume can give an indication of mass loss. How often is maintenance performed and are coatings reapplied? How much material is reapplied during maintenance?

Material composition coatings mast and (for offshore turbines) monopile • • • • •

What coatings are used? What is the layering of the coatings/in what order are the coatings applied? What is their material composition? Are any substances used that are listed on the ECHA candidate list of substances of very high concern (SVHC) If so, in what amount are they in the final product?

Insight in emission rates • Are there any available leaching rates for substances of very high concern out of the outer applied coatings (especially monopile coatings which are continuously exposed to seawater)? Leaching data preferable in weight per surface area per time • Data on material loss of coatings (weight loss/m2 over time) • Frequency of maintenance of masts • How much product is reapplied during maintenance? Internals Hydraulic oil • Does leakage of hydraulic oil occur? If so, in what amounts and how quickly? • Are any substances used that are listed on the ECHA candidate list of substances of very high concern (SVHC) • in what amounts are they in the final product? Electronic systems (e.g., transformers and distribution (sub)stations, cooling equipment) • How often are (parts of) electronic systems replaced? What SVHCs are present in those parts and in what amounts? • What kind of wear and tear are electronic systems exposed to? What are expected emissions for these parts? • What substances/formulations (mainly focused on SVHCcontaining formulations) are used in maintenance activities of electronic systems? • in what amounts are they in the final product? • For cooling systems specifically: what coolants are used and is information available on leakage over time? Do coolants contain SF6 or other F-gases? Use of galvanic anode cathodic protection for offshore

turbines • • •

Is galvanic anode cathodic protection still being used? Where? What and how much metal is used? What is the expected loss of material per year?

Pagina 40 van 49

RIVM-briefrapport 2022-0235

Tabel gevaarlijke stoffen in coatings Tabel S1 Gevaarlijke stoffen in coatings die gebruikt worden bij windturbines. Stoffen staan genoemd per coating en staan hierdoor vaak meerdere keren in de lijst. De betekenissen van de gevaarsklassen zijn te vinden op de website van UNECE:

https://unece.org/transport/standards/transport/dangerous-goods/ghs-rev9-2021 CAS Naam Aandeel in Aandeel in product product (min %) (max %) Polyurethaan coating voor de bladen 136210-30-5 tetraethyl-N,N'(methyleendicyclohexaan-4,1diyl)bis-DL-aspartaat 623-91-6 diethyl fumaraat

Lijst ZZS

Gevaarsklassen

25

30

nee

Skin sens. 1 H317, Aquatic Chronic 3 H412

1

5

nee

1

5

nee

0

1

nee

0

1

nee

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Acute Tox 4. H302, Skin Irrit. 2 H315, Eye Dam. 1 H318, STOT SE 3 H335 Skin Sens 1 H317, Aquatic Chronic 2 H411 Skin Sens 1 H317, Aquatic Acute 1 H400, Aquatic Chronic 1 H410 Skin Sens. 1 H317, Aquatic Acute 1 H400, Aquatic Chronic 1 H410 Gevaarsklassen

Primer/grondverf voor de bladen 1330-20-7 xyleen

40

100

nee

100-41-4

20

25

nee

NA 41556-26-7 82919-37-7 CAS

2-(2-Hydroxyphenyl)-2Hbenzotriazoles bis(1,2,2,6,6-pentamethyl-4piperidyl) sebacaat methyl-1,2,2,6,6-pentamethyl-4piperidylsebacaat Naam

ethylbenzeen

Pagina 41 van 49

Flam. Liq.3 H226, Acute Tox.4 H332, Acute Tox.4 H312, Skin Irrit.2 H315, Eye Irrit.2 H319, STOT SE3 H335, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Flam. Liq.2 H225, Acute Tox.4 H332, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412

RIVM-briefrapport 2022-0235

CAS

Naam

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

13822-56-5 5131-66-8 34590-94-8

3-(trimethoxysilyl)propylamine 1-butoxy-2-propanol dipropyleenglycolmethylether

1 1 1

3 5 5

nee nee nee

Skin Irrit.2 H315, Eye Dam.1 H318 Skin Irrit. 2 H315, Eye Irrit. 2 H319 EUH019

CAS

Naam

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

0

1

nee

0

1

nee

0

0.1

nee

0

0.1

nee

Skin Sens 1 H317, Aquatic Acute 1 H400, Aquatic Chronic 1 H410 Skin Sens. 1 H317, Aquatic Acute 1 H400, Aquatic Chronic 1 H410; Acute Tox. 2 H330, Acute Tox. 4 H302, Skin Irrit. 2 H315, Eye Dam. 1 H318, Skin Sens. 1 H317, Aquatic Acute 1 (M-Factor = 1) H400, Aquatic Chronic 2 H411 Acute Tox. 2 H330, Acute Tox. 2 H310, Acute Tox. 3 H301, Skin Corr. 1C H314, Eye Dam. 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 (MFactor = 100) H400, Aquatic Chronic 1 H410 (M-Factor = 100), EUH071

Polyacrylate coating voor op bladen, topcoat 41556-26-7 bis(1,2,2,6,6-pentamethyl-4piperidyl) sebacaat 82919-37-7 methyl-1,2,2,6,6-pentamethyl-4piperidylsebacaat 2634-33-5 1,2-benzo-isothiazoline-3-on

55965-84-9

Pagina 42 van 49

reactie massa van 5-chloro-2methyl-4-isothiazolin-3-een en 2methyl-2H -isothiazol-3-een

RIVM-briefrapport 2022-0235

CAS

Naam

Polyurethaan coating voor op de bladen 136210-30-5 tetraethyl-N,N'(methyleendicyclohexaan-4,1diyl)bis-DL-aspartaat 623-91-6 diethyl fumaraat NA 41556-26-7 82919-37-7 CAS

2-(2-Hydroxyphenyl)-2Hbenzotriazoles bis(1,2,2,6,6-pentamethyl-4piperidyl) sebacaat methyl-1,2,2,6,6-pentamethyl-4piperidylsebacaat Naam

Polyurethaan kit voor op de bladen 14464-46-1 silicium(di)oxide - cristoballiet 123-26-2 N,N'-ethane-1,2-diylbis(12hydroxyoctadecan-1-amide) 51287-84-4 Bis(dodecylthio)dimethylstannane

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

40

45

nee

Skin sens. 1 H317, Aquatic Chronic 3 H412

1

5

nee

1

5

nee

0

1

nee

0

1

nee

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Acute Tox 4. H302, Skin Irrit. 2 H315, Eye Dam. 1 H318, STOT SE 3 H335 Skin Sens 1, Aquatic Chronic 2; H317 H411 Skin Sens 1 H317, Aquatic Acute 1 H400, Aquatic Chronic 1 H410 Skin Sens. 1 H317, Aquatic Acute 1 H400, Aquatic Chronic 1 H410 Gevaarsklassen

5 0

10 1

ja nee

0

1

nee

Pagina 43 van 49

STOT RE 2 H373 Skin Sens. 1B H317, Aquatic Chronic 3 H412 Acute Tox. 4 H302, Skin Sens. 1A H317, Aquatic Chronic 3 H412

RIVM-briefrapport 2022-0235

CAS

Naam

Verharder voor polyurethaan kit 28182-81-2 hexamethylene di-isocyanate homopolymeer 822-06-0 hexamethylene di-isocyanate

CAS

Naam

Epoxy primer met zink voor op mast 7440-66-6 zinkpoeder - zinkstof (gestabiliseerd) 25068-38-6 epoxyhars met medium moleculair gewicht

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

95

100

nee

0

1

nee

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Acute Tox. 4 H332, Skin Sens. 1 H317, STOT SE 3 H335 Acute Tox. 1 H330, Acute Tox. 4 H302, Skin Irrit. 2 H315, Eye Irrit. 2 H319, Resp. Sens. 1 H334, Skin Sens. 1 H317, STOT SE 3 H335 Gevaarsklassen

50

75

nee

5

10

nee

1330-20-7

xyleen

5

10

nee

1314-13-2

zinkoxide

3

5

nee

71-36-3

butanol

1

3

nee

Pagina 44 van 49

Aquatic Acute 1 H400 (M=1), Aquatic Chronic 1 H410 (M=10) Skin Irrit. 2 H315, Eye Irrit. 2 H319, Skin Sens. 1 H317, Aquatic Chronic 2 H411 Flam. Liq.3 H226, Acute Tox.4 H332, Acute Tox.4 H312, Skin Irrit.2 H315, Eye Irrit.2 H319, STOT SE3 H335, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Aquatic Acute 1 H400, (M=1) Aquatic Chronic 1 H410 (M=1) Flam. Liq. 3 H226, Acute Tox. 4 H302, Skin Irrit. 2 H315, Eye Dam. 1 H318, STOT SE 3 H335, STOT SE 3 H336

RIVM-briefrapport 2022-0235

CAS

Naam

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

100-41-4

ethylbenzeen

1

3

nee

68609-97-2

oxiraan

1

3

nee

Flam. Liq.2 H225, Acute Tox.4 H332, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Skin Irrit. 2 H315, Skin Sens. 1 H317

CAS

Naam

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

Verharder voor epoxy primer 1330-20-7 xyleen

25

50

nee

107-98-2 100-41-4

1-methoxy-2-propanol ethylbenzeen

5 5

10 10

nee nee

90-72-2

5

10

nee

112-24-3

2,4,6tri(dimethylaminomethyl)fenol triethyleentetramine

1

2

nee

108-88-3

tolueen

0

1

nee

Flam. Liq.3 H226, Acute Tox.4 H332, Acute Tox.4 H312, Skin Irrit.2 H315, Eye Irrit.2 H319, STOT SE3 H335, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Flam. Liq. 3 H226, STOT SE 3 H336 Flam. Liq.2 H225, Acute Tox.4 H332, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Acute Tox. 4 H302, Skin Irrit 2 H315, Eye Irrit 2 H319 Acute Tox. 3 H311, Skin Corr. 1B H314, Eye Dam. 1 H318, Skin Sens. 1 H317, Aquatic Chronic 3 H412 Flam. Liq. 2 H225, Skin Irrit. 2 H315, Repr. 2 H361d, STOT SE 3 H336, STOT RE 2 H373, Asp. Tox. 1 H304

Pagina 45 van 49

RIVM-briefrapport 2022-0235

CAS

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

Epoxy coating mast, middenlaag 1675-54-3 bisfenol-A-epichloorhydrine (BADGE)

10

25

nee

1330-20-7

xyleen

5

10

nee

68512-30-1

Methylstyrenated phenol

5

10

nee

13463-67-7 100-51-6

titaniumdioxide fenylmethanol

3 1

5 3

nee nee

100-41-4

ethylbenzeen

1

3

nee

NA

1,3-bis(12hydroxyoctadecanamide-Nmathyle) benzene tolueen

0

1

nee

Skin Irrit. 2 H315, Eye Irrit. 2 H319, Skin Sens. 1 H317, Aquatic Chronic 2 H411 Flam. Liq.3 H226, Acute Tox.4 H332, Acute Tox.4 H312, Skin Irrit.2 H315, Eye Irrit.2 H319, STOT SE3 H335, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Skin Irrit. 2 H315, Skin Sens. 1B H317, Aquatic Chronic 3 H412 Carc. 2 H351 (inademing) Acute Tox. 4 H302, Acute Tox. 4 H332, Eye Irrit. 2 H319 Flam. Liq.2 H225, Acute Tox.4 H332, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Skin Sens. 1B H317, Aquatic Chronic 4 H413

0

0.3

nee

108-88-3

Pagina 46 van 49

Naam

Flam. Liq. 2 H225, Skin Irrit. 2 H315, Repr. 2 H361d, STOT SE 3 H336, STOT RE 2 H373, Asp. Tox. 1 H304

RIVM-briefrapport 2022-0235

CAS

Naam

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

Verharder voor epoxy coating 1330-20-7 xyleen

10

25

nee

68512-30-1

Methylstyrenated phenol

10

25

nee

71-36-3

butanol

5

10

nee

90-72-2

5

10

nee

100-51-6

2,4,6tri(dimethylaminomethyl)fenol fenylmethanol

3

5

nee

100-41-4

ethylbenzeen

1

3

nee

107-15-3

ethyleendiamine

0

1

Ja

112-24-3

triethyleentetramine

0

1

nee

Flam. Liq.3 H226, Acute Tox.4 H332, Acute Tox.4 H312, Skin Irrit.2 H315, Eye Irrit.2 H319, STOT SE3 H335, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Skin Irrit. 2 H315, Skin Sens. 1B H317, Aquatic Chronic 3 H412 Flam. Liq. 3, H226 Acute Tox. 4, H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Acute Tox. 4 H302, Skin Corr. 1C H314, Eye Dam. 1 H318 Acute Tox. 4 H302, Acute Tox. 4 H332, Eye Irrit. 2 H319 Flam. Liq.2 H225, Acute Tox.4 H332, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Flam. Liq. 3 H226, Acute Tox. 4 H302, Acute Tox. 3 H311, Acute Tox. 4 H332, Skin Corr. 1B H314, Eye Dam. 1 H318, Resp. Sens. 1B H334, Skin Sens. 1 H317, Aquatic Chronic 3 H412 Acute Tox. 3 H311, Skin Corr. 1B H314, Eye Dam. 1 H318, Skin Sens. 1 H317, Aquatic Chronic 3 H412

Pagina 47 van 49

RIVM-briefrapport 2022-0235

CAS

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

Polyurethaan coating mast, topcoat 13463-67-7 titaniumdioxide 64742-95-6 solvent-nafta (aardolie), licht aromatisch 1330-20-7 xyleen

10 15

25 20

nee Ja

10

25

nee

100-41-4

ethylbenzeen

1

3

nee

7779-90-0

trizinkbis(orthofosfaat)

1

3

nee

123-86-4

butylacetaat

1

3

nee

1065336-91-5

Reactie massa van bis (1,2,2,6,6pentamethyl4-piperidyl) sebacate en methyl 1,2,2,6,6pentamethyl4-piperidyl sebacaat 1,1,1-trimethylolpropane

0

1

nee

Carc. 2, H351 (inademing) Asp. Tox 1 H304, Muta. 1B H340, Carc. 1B Flam. Liq.3 H226, Acute Tox.4 H332, Acute Tox.4 H312, Skin Irrit.2 H315, Eye Irrit.2 H319, STOT SE3 H335, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Flam. Liq.2 H225, Acute Tox.4 H332, STOT RE2 H373, Asp. Tox.1 H304, Aquatic Chronic3 H412 Aquatic Acute 1, H400 (M=1) Aquatic Chronic 1, H410 (M=1) Flam. Liq. 3 H226, STOT SE 3 H336, EUH066 Skin Sens. 1A H317, Repr. 2 H361, Aquatic Acute 1 H400 (M=1), Aquatic Chronic 1 H410 (M=1)

0

0.3

nee

77-99-6

Pagina 48 van 49

Naam

Repr. 2 H361fd

RIVM-briefrapport 2022-0235

CAS

Naam

Aandeel in product (min %)

Aandeel in product (max %)

Lijst ZZS

Gevaarsklassen

Verharder voor polyurethaan topcoat 28182-81-2 hexamethylene di-isocyanate homopolymeer 123-86-4 butylacetaat

75

90

nee

5

10

nee

64742-95-6

oplosmiddel-nafta (aardolie), licht aromatisch

15

20

Ja

822-06-0

hexamethylene di-isocyanate

0

0.3

nee

Acute Tox. 4 H332, Skin Sens. 1 H317, STOT SE 3 H335 Flam. Liq. 3 H226, STOT SE 3 H336, EUH066 Flam. Liq. 3 H226, STOT SE 3 H335, STOT SE 3 H336, Asp. Tox. 1 H304, Aquatic Chronic 2 H411 Acute Tox. 1 H330, Acute Tox. 4 H302, Skin Irrit. 2 H315, Eye Irrit. 2 H319, Resp. Sens. 1 H334, Skin Sens. 1 H317, STOT SE 3 H335

Pagina 49 van 49

Dit is een uitgave van: Rijksinstituut voor Volksgezondheid en Milieu Postbus 1 | 3720 BA Bilthoven www.rivm.nl maart 2023

De zorg voor morgen begint vandaag